Improvement measures for corrosion of tundish stopper
1. Strictly control the slag from the big bag
The main sources of slag components in the casting area of the tundish are ladle refining slag, tundish covering agent and molten steel inclusions floating up into the slag layer. Among them, the low silicon aluminum killed steel refining slag,
which is more severely corroded by the stopper rod, is a high basicity
refining slag system, and the CaO content in the slag is controlled at
55%-65%. The large ladle slag of each furnace will form a refined slag
enrichment in the injection point area of the tundish. During the
subcontracting process and when the pouring steel stream impacts the
slag surface of the injection point area, it will cause the refined slag
to enter the casting area and cause erosion of the stopper.
Therefore, it is necessary to strictly control the slagging of the big
ladle, and use the automatic control of the slag detection to avoid a
large amount of slagging at the end of pouring. At the same time, the
tundish slagging operation should be adopted. When the large ladle is
continuously pouring 5 to 7 furnaces of molten steel, the tundish level
slagging operation should be carried out to control the thickness of the
slag layer in the injection point area.
2. Control the superheat of the package
The liquidus line of the molten steel of XGM6-1 steel grade is 1535℃,
and the superheat is controlled at 25~45℃. From the actual production
process, when the average superheat of the tundish reaches 45℃ (the
temperature of the tundish is 1580℃), all slag lines appear erosion off
the situation. The average superheat of the tundish is reduced by 15℃,
and the actual control average tundish temperature is reduced to about
1560~1565℃. The erosion of the slag line has been significantly
improved, and the erosion rate of the monoblock stopper slag line can be stably controlled within 20%.
3. Optimizing the composition of the covering agent for tundish molten steel
In view of the reaction situation between the tundish slag and the
stopper slag line, it is impossible to completely avoid the problem of
refined slag entering the casting area and high superheat of the tundish
in the actual production process. Therefore, the composition of the
covering agent for the tundish molten steel is optimized for different
steel grades. The temperature condition of the package increases the MgO
content in the covering agent, and forms the Mg-Ca-Al-Si multi-element
compound in the slag layer of the middle cladding. The melting point is
above 1600℃. A protective layer is formed at the slag line of the
stopper to slow down the damage of the slag. The rod body is resistant
to corrosion.
The control of the MgO content in the covering agent needs to be
adjusted according to the actual control range of the molten steel
ladle. When the MgO content exceeds 15%, the melting point of the
tundish slag will increase significantly. The slag layer in the ladle
pouring area is crusted, which affects the normal stopper control.
By optimizing the composition of the tundish covering agent, a coating layer of high-melting compound mainly composed of MgO is formed at the slag line of the monoblock stopper rod, which prevents the slag-steel interface reaction from corroding the refractory material at the slag line and effectively improves the service life of the stopper.
Wanhao is a manufacturer who is specialized in designing various kinds of furnace and making refractory products for electric furnace, ladle, tundish, blast furnace, AOD furnace, IF furnace, etc.
Article Source:Main tasks of the electric furnace during the oxidation period and reduction period
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